An eleven-vertex metallaborane with tetracapped pentagonal bipyramidal geometry.
نویسندگان
چکیده
A metallaborane of novel structure, [(Cp*Mo)(2)B(3)H(3)Se(2){Fe(CO)(2)}(2){Fe(CO)(3)}(2)] (2; Cp* = η(5)-C(5)Me(5)), with tetracapped pentagonal bipyramidal geometry, isolated from the reaction of [(Cp*Mo)(2)B(4)H(4)Se(2)], 1 with [Fe(2)(CO)(9)]; the title compound exhibit an 11-vertex closo-cage geometry, having eight skeletal electron pairs (sep) and 98 valence electrons, appropriate for its geometric structure.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 41 13 شماره
صفحات -
تاریخ انتشار 2012